Information card for entry 4028829

Structure parameters

• Chemical name: (<i>E</i>)-1-((<i>tert</i>-butyldiphenylsilyl)methylene)-2-(2,4-dinitrophenyl)hydrazine
• Formula: C23 H24 N4 O4 Si
• Calculated formula: C23 H24 N4 O4 Si
• SMILES: [Si](/C=N/Nc1c(N(=O)=O)cc(N(=O)=O)cc1)(C(C)(C)C)(c1ccccc1)c1ccccc1
• Title of publication: Synthesis of Formylsilanes through Oxidative Cleavage of α-Silyl Glycols
• Authors of publication: Henrik von Wachenfeldt; Daniel Strand
• Journal of publication: Journal of Organic Chemistry
• Year of publication: 2013
• Journal volume: 78
• Pages of publication: 12268 - 12273
• a: 37.0549 ± 0.0018 Å
• b: 7.4656 ± 0.0003 Å
• c: 17.9306 ± 0.0008 Å
• α: 90°
• β: 113.023 ± 0.005°
• γ: 90°
• Cell volume: 4565.2 ± 0.4 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0942
• Residual factor for significantly intense reflections: 0.0524
• Weighted residual factors for significantly intense reflections: 0.1061
• Weighted residual factors for all reflections included in the refinement: 0.1259
• Goodness-of-fit parameter for all reflections included in the refinement: 1.018
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No