Diastereoselective Synthesis of P-Stereogenic Secondary Phosphine Oxides (SPOs) Bearing a Chiral Substituent by Ring Opening of (+)-Limonene Oxide with Primary Phosphido Nucleophiles.
Authors of publication
Zimmerman, Amber; Xu, Rebecca; Reynolds, Samantha C.; Shipp, Chase; Marshall, Derrick; Wang, Ge; Blank, Natalia F.; Gibbons, Sarah; Hughes, Russell P.; Glueck, David S.; Balaich, Gary James; Rheingold, Arnold L.
Journal of publication
The Journal of organic chemistry
Year of publication
2020
a
11.0048 ± 0.0002 Å
b
11.0048 ± 0.0002 Å
c
17.676 ± 0.0003 Å
α
90°
β
90°
γ
120°
Cell volume
1853.87 ± 0.06 Å3
Cell temperature
100 K
Ambient diffraction temperature
100 K
Number of distinct elements
4
Space group number
145
Hermann-Mauguin space group symbol
P 32
Hall space group symbol
P 32
Residual factor for all reflections
0.0269
Residual factor for significantly intense reflections
0.0266
Weighted residual factors for significantly intense reflections
0.0693
Weighted residual factors for all reflections included in the refinement
0.0697
Goodness-of-fit parameter for all reflections included in the refinement
