Diastereoselective Synthesis of P-Stereogenic Secondary Phosphine Oxides (SPOs) Bearing a Chiral Substituent by Ring Opening of (+)-Limonene Oxide with Primary Phosphido Nucleophiles.
Authors of publication
Zimmerman, Amber; Xu, Rebecca; Reynolds, Samantha C.; Shipp, Chase; Marshall, Derrick; Wang, Ge; Blank, Natalia F.; Gibbons, Sarah; Hughes, Russell P.; Glueck, David S.; Balaich, Gary James; Rheingold, Arnold L.
Journal of publication
The Journal of organic chemistry
Year of publication
2020
a
5.9712 ± 0.0009 Å
b
12.238 ± 0.002 Å
c
22.345 ± 0.004 Å
α
90°
β
90°
γ
90°
Cell volume
1632.9 ± 0.5 Å3
Cell temperature
100 K
Ambient diffraction temperature
100 K
Number of distinct elements
4
Space group number
19
Hermann-Mauguin space group symbol
P 21 21 21
Hall space group symbol
P 2ac 2ab
Residual factor for all reflections
0.0409
Residual factor for significantly intense reflections
0.0365
Weighted residual factors for significantly intense reflections
0.0865
Weighted residual factors for all reflections included in the refinement
0.089
Goodness-of-fit parameter for all reflections included in the refinement
