Information card for entry 4062108

Structure parameters

• Formula: C52 H44 Fe4 O28 P2 Re4 Te4
• Calculated formula: C52 H44 Fe4 O28 P2 Re4 Te4
• SMILES: C(#[O])[Re]1([P](C2CCCCC2)(C2CCCCC2)[Re](C#[O])(C#[O])(C#[O])(C#[O])[Te]21[Fe]1(C#[O])(C#[O])([Fe]2(C#[O])(C#[O])(C#[O])[Te]1[Te]1[Fe]3(C#[O])(C#[O])(C#[O])[Fe]1(C#[O])(C#[O])(C#[O])[Te]13[Re](C#[O])(C#[O])(C#[O])(C#[O])[P](C2CCCCC2)(C2CCCCC2)[Re]1(C#[O])(C#[O])(C#[O])C#[O])C#[O])(C#[O])(C#[O])C#[O]
• Title of publication: Chalcogen centered spirocyclic mixed metal carbonyl complexes: Synthesis and molecular structures of (CO)~8~(μ-PCy~2~)Re~2~(μ~4~-E)Fe~2~(μ-ER)(CO)~6~ and ((CO)~8~(μ-PCy~2~)Re~2~(μ~4~-E)Fe~2~(CO)~6~)~2~(μ~4~-E~2~) (E = S, Se, Te; R = org. residue)
• Authors of publication: Klose, Stefanie; Flörke, Ulrich; Mathur, Pradeep; Egold, Hans
• Journal of publication: Organometallics
• Year of publication: 2003
• a: 9.351 ± 0.002 Å
• b: 12.026 ± 0.003 Å
• c: 17.27 ± 0.004 Å
• α: 108.91 ± 0.004°
• β: 90.285 ± 0.004°
• γ: 102.955 ± 0.004°
• Cell volume: 1784 ± 0.7 ų
• Cell temperature: 153 ± 2 K
• Ambient diffraction temperature: 153 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No