Information card for entry 4062345

Structure parameters

• Common name: {[(Ph3P)Au]2C(SO2Ph)CN[Au(PPh3)]}+BF4-
• Formula: C62 H50 Au3 B F4 N O2 P3 S
• Calculated formula: C62 H50 Au3 B F4 N O2 P3 S
• SMILES: [B](F)(F)(F)[F-].[Au]1([P](c2ccccc2)(c2ccccc2)c2ccccc2)[Au]([P](c2ccccc2)(c2ccccc2)c2ccccc2)C1(S(=O)(=O)c1ccccc1)C#[N][Au][P](c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Dinuclear Gold(I) "A-Frame" Complexes from Geminal Diauration of 2,4-Diketones, Methylene-Disulfones and Cyanomethylsulfones
• Authors of publication: H. Schmidbaur; B. Djordjevic; K. A. Porter; A. Schier; S. Nogai
• Journal of publication: Organometallics
• Year of publication: 2003
• a: 18.1884 ± 0.0002 Å
• b: 20.3524 ± 0.0002 Å
• c: 22.4324 ± 0.0003 Å
• α: 110.954 ± 0.0004°
• β: 96.8981 ± 0.0005°
• γ: 104.373 ± 0.0009°
• Cell volume: 7309.09 ± 0.15 ų
• Cell temperature: 143 ± 2 K
• Ambient diffraction temperature: 143 ± 2 K
• Number of distinct elements: 9
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No