Information card for entry 4062831

Structure parameters

• Formula: C27 H57 B F4 N O0.5 Os P2
• Calculated formula: C27 H57 B F4 N O0.5 Os P2
• SMILES: [OsH3]12([P](C(C)C)(C(C)C)C(C)C)([P](C(C)C)(C(C)C)C(C)C)[n]3c([CH]1=[CH2]2)cccc3.[B](F)(F)(F)[F-].O(CC)CC
• Title of publication: Activation of C(sp2)-H and Reduction of C=E (E = CH, N) Bonds with an Osmium-hexahydride Complex: Influence of E on the Behavior of RCH=E-py Substrates
• Authors of publication: Barrio, M. P.; Esteruelas, M. A.; Oñate, E.
• Journal of publication: Organometallics
• Year of publication: 2004
• a: 8.947 ± 0.002 Å
• b: 11.992 ± 0.003 Å
• c: 32.215 ± 0.008 Å
• α: 84.276 ± 0.004°
• β: 83.4 ± 0.004°
• γ: 69.593 ± 0.004°
• Cell volume: 3211.2 ± 1.3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No