Information card for entry 4063098

Structure parameters

• Common name: [CpRu(CH3CN)(mue-SPh)2(CH3CN)RuCp](PF6)2.solv
• Formula: C26 H26 F12 N2 P2 Ru2 S2
• Calculated formula: C26 H26 F12 N2 P2 Ru2 S2
• SMILES: [Ru]123456([Ru]789%10([S]1c1ccccc1)([S]2c1ccccc1)([N]#CC)[cH]1[cH]7[cH]8[cH]9[cH]%101)([N]#CC)[cH]1[cH]3[cH]4[cH]5[cH]61.[P](F)(F)(F)(F)(F)[F-].[P](F)(F)(F)(F)(F)[F-]
• Title of publication: Facile S-S Bond Activation of Alkyl and Aryl Disulfides by [RuCp(CH3CN)3]+ - Formation of Dinuclear Ru(III)-Ru(III) Complexes with Bridging Thiolate Ligands
• Authors of publication: Eva Becker; Kurt Mereiter; Roland Schmid; Karl Kirchner
• Journal of publication: Organometallics
• Year of publication: 2004
• a: 12.8205 ± 0.0007 Å
• b: 23.4042 ± 0.0012 Å
• c: 12.9987 ± 0.0007 Å
• α: 90°
• β: 108.287 ± 0.001°
• γ: 90°
• Cell volume: 3703.3 ± 0.3 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No