Information card for entry 4063233

Structure parameters

• Common name: [{K(MesNPPh2CHPPh2NMes)}2]. 3(toluene)
• Formula: C107 H110 K2 N4 P4
• Calculated formula: C107 H94 K2 N4 P4
• Title of publication: Synthesis and M-Cγ Hemilability of Group 2 Bis(phosphinimino)methanides
• Authors of publication: Shabana A. Ahmed; Michael S. Hill; Peter B. Hitchcock
• Journal of publication: Organometallics
• Year of publication: 2006
• Journal volume: 25
• Journal issue: 2
• Pages of publication: 394 - 402
• a: 14.4977 ± 0.0002 Å
• b: 14.6883 ± 0.0002 Å
• c: 25.7312 ± 0.0005 Å
• α: 100.458 ± 0.001°
• β: 94.304 ± 0.001°
• γ: 119.129 ± 0.001°
• Cell volume: 4620.91 ± 0.13 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.2117
• Residual factor for significantly intense reflections: 0.1318
• Weighted residual factors for significantly intense reflections: 0.2732
• Weighted residual factors for all reflections included in the refinement: 0.306
• Goodness-of-fit parameter for all reflections included in the refinement: 1.185
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No