Information card for entry 4063954

Structure parameters

• Formula: C34 H50 O Os P2
• Calculated formula: C34 H50 O Os P2
• SMILES: [Os]12345678(C(=C)P9(=O)[C]1(=[CH]3[CH]4=[C]29C1CCCCC1)C1CCCCC1)P1[C]6(=[CH]7[CH]8=[C]51C1CCCCC1)C1CCCCC1
• Title of publication: Preparation of Osmium η5-Phospholide Complexes and Their Reactions with Acyl Electrophiles: C═O Bond Cleavage and C−C Bond Formation within the Metal Coordination Sphere
• Authors of publication: Ogasawara, Masamichi; Shintani, Minoru; Watanabe, Susumu; Sakamoto, Takeshi; Nakajima, Kiyohiko; Takahashi, Tamotsu
• Journal of publication: Organometallics
• Year of publication: 2011
• Journal volume: 30
• Journal issue: 6
• Pages of publication: 1487
• a: 12.1843 ± 0.0009 Å
• b: 20.2214 ± 0.0015 Å
• c: 13.8982 ± 0.001 Å
• α: 90°
• β: 109.942 ± 0.0016°
• γ: 90°
• Cell volume: 3219 ± 0.4 ų
• Cell temperature: 298.1 K
• Ambient diffraction temperature: 298 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/a 1
• Hall space group symbol: -P 2yab
• Residual factor for significantly intense reflections: 0.0472
• Weighted residual factors for all reflections included in the refinement: 0.0967
• Goodness-of-fit parameter for all reflections included in the refinement: 1.084
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No