Information card for entry 4064048

Structure parameters

• Formula: C24 H52 N4 O4 Zn4
• Calculated formula: C24 H52 N4 O4 Zn4
• SMILES: [Zn]12([O]3[Zn]4([N](=C([O]5[Zn]([N](=C([O]1[Zn]5([N](=C3C)C(C)C)C)C)C(C)C)(C)[O]4C(=[N]2C(C)C)C)C)C(C)C)C)C
• Title of publication: Insertion Reactions of Heterocumulenes into Zn−C Bonds: Synthesis and Structural Characterization of Multinuclear Zinc Amidate Complexes
• Authors of publication: Schmidt, Sarah; Schäper, Raphaela; Schulz, Stephan; Bläser, Dieter; Wölper, Christoph
• Journal of publication: Organometallics
• Year of publication: 2011
• Journal volume: 30
• Journal issue: 5
• Pages of publication: 1073
• a: 11.3409 ± 0.0005 Å
• b: 11.8633 ± 0.0005 Å
• c: 13.2487 ± 0.0005 Å
• α: 74.605 ± 0.002°
• β: 82.448 ± 0.002°
• γ: 76.447 ± 0.002°
• Cell volume: 1666.11 ± 0.12 ų
• Cell temperature: 100 ± 1 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0224
• Residual factor for significantly intense reflections: 0.0197
• Weighted residual factors for significantly intense reflections: 0.0501
• Weighted residual factors for all reflections included in the refinement: 0.0515
• Goodness-of-fit parameter for all reflections included in the refinement: 1.085
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No