Information card for entry 4064699

Structure parameters

• Common name: Pt-complex
• Chemical name: Pt-complex
• Formula: C19 H24 N2 O4 Pt S
• Calculated formula: C19 H24 N2 O4 Pt S
• SMILES: [Pt]123([CH]4=[CH]1C2CCCCC4)[n]1c(C(S(=O)(=O)[O-])c2[n]3cccc2)cccc1.O
• Title of publication: Allylic C‒H Deprotonation of Olefins with PtII(OH) to Form η3-Allyl PtIIComplexes in Water and Aprotic Organic Solvents
• Authors of publication: Khusnutdinova, Julia R.; Zavalij, Peter Y.; Vedernikov, Andrei N.
• Journal of publication: Organometallics
• Year of publication: 2011
• Journal volume: 30
• Journal issue: 12
• Pages of publication: 3392
• a: 9.3702 ± 0.0009 Å
• b: 9.502 ± 0.0009 Å
• c: 11.3905 ± 0.0011 Å
• α: 72.504 ± 0.002°
• β: 88.877 ± 0.002°
• γ: 81.837 ± 0.002°
• Cell volume: 957.16 ± 0.16 ų
• Cell temperature: 220 ± 2 K
• Ambient diffraction temperature: 220 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0334
• Residual factor for significantly intense reflections: 0.0295
• Weighted residual factors for significantly intense reflections: 0.075
• Weighted residual factors for all reflections included in the refinement: 0.0771
• Goodness-of-fit parameter for all reflections included in the refinement: 1
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No