Information card for entry 4064743

Structure parameters

• Formula: C17 H46 Cl2 O3 P4 Rh2
• Calculated formula: C17 H46 Cl2 O3 P4 Rh2
• SMILES: [Rh]1(Cl)([P](C)(C)C)([P](C)(C)C)([O]2[Rh](Cl)([P](C)(C)C)([P](C)(C)C)([O]=C2O1)CC)CC
• Title of publication: Synthesis of a Rhodium(III) Diethyl μ-Carbonato Complex in the Reaction of CO2, H2O, and Ethylene
• Authors of publication: Choi, Jun-Chul; Kohno, Kazufumi; Otsuka, Michiko; Yasuda, Hiroyuki; Sakakura, Toshiyasu
• Journal of publication: Organometallics
• Year of publication: 2011
• Journal volume: 30
• Journal issue: 22
• Pages of publication: 6060
• a: 9.0624 ± 0.0017 Å
• b: 9.795 ± 0.0019 Å
• c: 17.009 ± 0.003 Å
• α: 103.47 ± 0.003°
• β: 100.754 ± 0.003°
• γ: 94.784 ± 0.004°
• Cell volume: 1429.7 ± 0.5 ų
• Cell temperature: 183 ± 2 K
• Ambient diffraction temperature: 183 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0433
• Residual factor for significantly intense reflections: 0.041
• Weighted residual factors for significantly intense reflections: 0.1112
• Weighted residual factors for all reflections included in the refinement: 0.1146
• Goodness-of-fit parameter for all reflections included in the refinement: 1.031
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No