Information card for entry 4064745

Structure parameters

• Formula: C13 H38 Cl4 P4 Rh2
• Calculated formula: C13 H38 Cl4 P4 Rh2
• SMILES: [Rh]12([Cl][Rh]([Cl]1)(Cl)([P](C)(C)C)([P](C)(C)C)C2)(Cl)([P](C)(C)C)[P](C)(C)C
• Title of publication: Synthesis of a Rhodium(III) Diethyl μ-Carbonato Complex in the Reaction of CO2, H2O, and Ethylene
• Authors of publication: Choi, Jun-Chul; Kohno, Kazufumi; Otsuka, Michiko; Yasuda, Hiroyuki; Sakakura, Toshiyasu
• Journal of publication: Organometallics
• Year of publication: 2011
• Journal volume: 30
• Journal issue: 22
• Pages of publication: 6060
• a: 17.9556 ± 0.0017 Å
• b: 9.898 ± 0.0009 Å
• c: 14.285 ± 0.0013 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 2538.8 ± 0.4 ų
• Cell temperature: 183 ± 2 K
• Ambient diffraction temperature: 183 ± 2 K
• Number of distinct elements: 5
• Space group number: 29
• Hermann-Mauguin space group symbol: P c a 21
• Hall space group symbol: P 2c -2ac
• Residual factor for all reflections: 0.0148
• Residual factor for significantly intense reflections: 0.0146
• Weighted residual factors for significantly intense reflections: 0.0375
• Weighted residual factors for all reflections included in the refinement: 0.0376
• Goodness-of-fit parameter for all reflections included in the refinement: 1.039
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No