Information card for entry 4068052

Structure parameters

• Formula: C52 H82 Cl2 N8 Si4
• Calculated formula: C52 H82 Cl2 N8 Si4
• SMILES: C1(c2ccccc2)=[N](C(C)(C)C)[Si]2(N1C(C)(C)C)(N(/N=C/[Si](C)(C)C)[Si]1([N](=C(c3ccccc3)N1C(C)(C)C)C(C)(C)C)(N2/N=C/[Si](C)(C)C)Cl)Cl.c1(ccccc1)C.c1(ccccc1)C
• Title of publication: A Remarkable End-On Activation of Diazoalkane and Cleavage of Both C‒Cl Bonds of Dichloromethane with a Silylene to a Single Product with Five-Coordinate Silicon Atoms
• Authors of publication: Sen, Sakya S.; Hey, Jakob; Kratzert, Daniel; Roesky, Herbert W.; Stalke, Dietmar
• Journal of publication: Organometallics
• Year of publication: 2012
• Journal volume: 31
• Journal issue: 1
• Pages of publication: 435
• a: 12.613 ± 0.002 Å
• b: 11.307 ± 0.002 Å
• c: 21.148 ± 0.002 Å
• α: 90°
• β: 104.57 ± 0.02°
• γ: 90°
• Cell volume: 2919 ± 0.8 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0526
• Residual factor for significantly intense reflections: 0.0404
• Weighted residual factors for significantly intense reflections: 0.0993
• Weighted residual factors for all reflections included in the refinement: 0.1101
• Goodness-of-fit parameter for all reflections included in the refinement: 1.059
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No