Information card for entry 4068115

Structure parameters

• Chemical name: pentacarbonyl(bromo(dimethyl)stibine)manganese(I) trifluoromethanesulfonate
• Formula: C8 H6 Br F3 Mn O8 S Sb
• Calculated formula: C8 H6 Br F3 Mn O8 S Sb
• SMILES: [Mn]([Sb](Br)(C)C)(C#[O])(C#[O])(C#[O])(C#[O])C#[O].S(=O)(=O)(C(F)(F)F)[O-]
• Title of publication: Halostibines SbMeX2and SbMe2X: Lewis Acids or Lewis Bases?
• Authors of publication: Benjamin, Sophie L.; Levason, William; Reid, Gillian; Warr, Robert P.
• Journal of publication: Organometallics
• Year of publication: 2012
• Journal volume: 31
• Journal issue: 3
• Pages of publication: 1025
• a: 13.023 ± 0.002 Å
• b: 7.6958 ± 0.0014 Å
• c: 16.455 ± 0.003 Å
• α: 90°
• β: 93.553 ± 0.007°
• γ: 90°
• Cell volume: 1646 ± 0.5 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0666
• Residual factor for significantly intense reflections: 0.0608
• Weighted residual factors for significantly intense reflections: 0.1541
• Weighted residual factors for all reflections included in the refinement: 0.1584
• Goodness-of-fit parameter for all reflections included in the refinement: 1.128
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No