Information card for entry 4068463

Structure parameters

• Chemical name: Bis[di(η^5^-cyclopentadienyl)molybdenum(μ-bismuth-tert- butyldimethylsilanolat)]
• Formula: C32 H50 Bi2 Mo2 O2 Si2
• Calculated formula: C32 H50 Bi2 Mo2 O2 Si2
• SMILES: [cH]12[cH]3[cH]4[cH]5[cH]1[Mo]167892345([cH]2[cH]1[cH]6[cH]7[cH]92)[Bi](O[Si](C)(C)C(C)(C)C)[Mo]12345679([cH]%10[cH]4[cH]3[cH]2[cH]1%10)([cH]1[cH]5[cH]6[cH]7[cH]91)[Bi]8O[Si](C)(C)C(C)(C)C
• Title of publication: Opening of Bent Bi−C Bonds by Silanols To Give Stable Cp2Mo(μ-BiOR)2MoCp2Complexes
• Authors of publication: Knispel, Christina; Limberg, Christian; Mehring, Michael
• Journal of publication: Organometallics
• Year of publication: 2009
• Journal volume: 28
• Journal issue: 2
• Pages of publication: 646
• a: 11.2536 ± 0.0006 Å
• b: 11.0845 ± 0.0007 Å
• c: 14.515 ± 0.001 Å
• α: 90°
• β: 107.818 ± 0.005°
• γ: 90°
• Cell volume: 1723.76 ± 0.19 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0622
• Residual factor for significantly intense reflections: 0.0494
• Weighted residual factors for significantly intense reflections: 0.0966
• Weighted residual factors for all reflections included in the refinement: 0.1
• Goodness-of-fit parameter for all reflections included in the refinement: 1.194
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No