Information card for entry 4068592

Structure parameters

• Formula: C35 H32 Cl2 N2 Pt Si
• Calculated formula: C35 H32 Cl2 N2 Pt Si
• SMILES: [PtH2]1([Si](c2ccccc2)(c2ccccc2)c2ccccc2)[N](=C(C=C(N1c1ccc(Cl)cc1)C)C)c1ccc(Cl)cc1
• Title of publication: Cycloaddition Reactions of Terminal Alkynes and Phosphaalkynes with an Isolable 5-Coordinate β-Diiminate Platinum(IV) Dihydrosilyl Complex
• Authors of publication: West, Nathan M.; White, Peter S.; Templeton, Joseph L.; Nixon, John F.
• Journal of publication: Organometallics
• Year of publication: 2009
• Journal volume: 28
• Journal issue: 5
• Pages of publication: 1425
• a: 9.841 ± 0.002 Å
• b: 11.172 ± 0.002 Å
• c: 14.862 ± 0.003 Å
• α: 88.797 ± 0.009°
• β: 82.253 ± 0.007°
• γ: 73.627 ± 0.006°
• Cell volume: 1553.2 ± 0.5 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.025
• Residual factor for significantly intense reflections: 0.0236
• Weighted residual factors for significantly intense reflections: 0.0756
• Weighted residual factors for all reflections included in the refinement: 0.0875
• Goodness-of-fit parameter for all reflections included in the refinement: 1.126
• Diffraction radiation wavelength: 1.54178 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No