Information card for entry 4069224

Structure parameters

• Common name: 2 (dppe)Pd(SeTrip)_0.75 CCl2
• Chemical name: 2 (dppe)Pd(SeTrip)_0.75 CH2Cl2
• Formula: C46.75 H37 Cl1.5 P2 Pd Se
• Calculated formula: C46.75 H37 Cl1.5 P2 Pd Se
• Title of publication: Reactions of 9-Triptyceneselenol with Palladium(0) Complexes: Unexpected Formations of the Dinuclear Palladium(I) Complex [{Pd(PPh3)}2(μ-SeTrip)2] and Five-Membered Selenapalladacycle [Pd(η2(C,Se)-Trip)(dppe)]
• Authors of publication: Nakata, Norio; Uchiumi, Rei; Yoshino, Tomoharu; Ikeda, Takashige; Kamon, Hitomi; Ishii, Akihiko
• Journal of publication: Organometallics
• Year of publication: 2009
• Journal volume: 28
• Journal issue: 7
• Pages of publication: 1981
• a: 14.2418 ± 0.0007 Å
• b: 17.8246 ± 0.0008 Å
• c: 18.616 ± 0.0009 Å
• α: 61.903 ± 0.001°
• β: 77.52 ± 0.001°
• γ: 66.942 ± 0.001°
• Cell volume: 3832.9 ± 0.3 ų
• Cell temperature: 103 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0604
• Residual factor for significantly intense reflections: 0.0422
• Weighted residual factors for significantly intense reflections: 0.0949
• Weighted residual factors for all reflections included in the refinement: 0.104
• Goodness-of-fit parameter for all reflections included in the refinement: 1.021
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No