Information card for entry 4069405

Structure parameters

• Formula: C32 H46 O Ru Si2
• Calculated formula: C32 H46 O Ru Si2
• SMILES: [Ru]1234(=[Si](c5c(cc(cc5C)C)C)c5c(cc(cc5C)C)C)([Si](C)(C)C)(C#[O])[c]5([c]1([c]2([c]3([c]45C)C)C)C)C
• Title of publication: Synthesis and Properties of a Silyl(silylene)ruthenium Complex: Activation Barrier of the Ru═Si Bond Rotation and Facile Replacement of the Methyl Groups with Alkoxy Groups of a Silyl Ligand
• Authors of publication: Hashimoto, Hisako; Sato, Jun; Tobita, Hiromi
• Journal of publication: Organometallics
• Year of publication: 2009
• Journal volume: 28
• Journal issue: 14
• Pages of publication: 3963
• a: 10.5565 ± 0.0003 Å
• b: 18.7387 ± 0.0007 Å
• c: 15.7809 ± 0.0006 Å
• α: 90°
• β: 95.1401 ± 0.0013°
• γ: 90°
• Cell volume: 3109.15 ± 0.19 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.042
• Residual factor for significantly intense reflections: 0.0339
• Weighted residual factors for significantly intense reflections: 0.0881
• Weighted residual factors for all reflections included in the refinement: 0.1004
• Goodness-of-fit parameter for all reflections included in the refinement: 1.176
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No