Information card for entry 4071405

Structure parameters

• Formula: C46 H46 P2 Rh Si2
• Calculated formula: C46 H46 P2 Rh Si2
• SMILES: [Rh]1([P](c2ccccc2)(c2ccccc2)c2ccccc2)([P](c2ccccc2)(c2ccccc2)c2ccccc2)[Si](c2c([Si]1(C)C)cccc2)(C)C
• Title of publication: “Synergistic Effects of Two Si−H Groups and a Metal Center” in Transition Metal-Catalyzed Hydrosilylation of Unsaturated Molecules: A Mechanistic Study of the RhCl(PPh3)3-Catalyzed Hydrosilylation of Ketones with 1,2-Bis(dimethylsilyl)benzene
• Authors of publication: Sunada, Yusuke; Fujimura, Yoshiki; Nagashima, Hideo
• Journal of publication: Organometallics
• Year of publication: 2008
• Journal volume: 27
• Journal issue: 14
• Pages of publication: 3502
• a: 10.7863 ± 0.0011 Å
• b: 17.5377 ± 0.0018 Å
• c: 21.737 ± 0.002 Å
• α: 90°
• β: 101.979 ± 0.0014°
• γ: 90°
• Cell volume: 4022.4 ± 0.7 ų
• Cell temperature: 123.1 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for significantly intense reflections: 0.0685
• Weighted residual factors for all reflections included in the refinement: 0.1573
• Goodness-of-fit parameter for all reflections included in the refinement: 1.105
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No