Information card for entry 4073074

Structure parameters

• Common name: Cobalt(II) Mesitylglyoxime Pyridine
• Chemical name: trans-bis(dimesitylglyoximato)-(pyridine)-cobalt(II)
• Formula: C50 H56 Co N6 O4
• Calculated formula: C50 H56 Co N6 O4
• SMILES: [Co]12([N](O)=C(C(=N1=O)c1c(cc(cc1C)C)C)c1c(cc(cc1C)C)C)([N](O)=C(C(=N2=O)c1c(cc(cc1C)C)C)c1c(cc(cc1C)C)C)([n]1ccccc1)[n]1ccccc1
• Title of publication: Co−C Bond Homolysis: Reactivity Difference between Alkyl- and Benzylcobaloximes
• Authors of publication: Mandal, Debaprasad; Bhuyan, Mouchumi; Laskar, Moitree; Gupta, B. D.
• Journal of publication: Organometallics
• Year of publication: 2007
• Journal volume: 26
• Journal issue: 11
• Pages of publication: 2795
• a: 12.128 ± 0.002 Å
• b: 31.999 ± 0.009 Å
• c: 12.13 ± 0.002 Å
• α: 90 ± 0.018°
• β: 98.012 ± 0.015°
• γ: 90 ± 0.002°
• Cell volume: 4661.5 ± 1.7 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: I 1 2/a 1
• Hall space group symbol: -I 2ya
• Residual factor for all reflections: 0.126
• Residual factor for significantly intense reflections: 0.0621
• Weighted residual factors for significantly intense reflections: 0.1599
• Weighted residual factors for all reflections included in the refinement: 0.1731
• Goodness-of-fit parameter for all reflections included in the refinement: 1.018
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No