Facile Transformations of a 1,3,5-Triphosphacyclohexadienyl Anion within the Coordination Sphere of Group 13 and 14 Elements: Synthesis of 1,3-Diphosphacyclopentadienyl Complexes and Phosphaorganometallic Cage Compounds
Authors of publication
Brym, Markus; Francis, Matthew D.; Jin, Guoxia; Jones, Cameron; Mills, David P.; Stasch, Andreas
Journal of publication
Organometallics
Year of publication
2006
Journal volume
25
Journal issue
20
Pages of publication
4799
a
34.278 ± 0.007 Å
b
18.508 ± 0.004 Å
c
11.287 ± 0.002 Å
α
90°
β
97.78 ± 0.03°
γ
90°
Cell volume
7095 ± 3 Å3
Cell temperature
150 ± 2 K
Ambient diffraction temperature
150 ± 2 K
Number of distinct elements
4
Space group number
15
Hermann-Mauguin space group symbol
C 1 2/c 1
Hall space group symbol
-C 2yc
Residual factor for all reflections
0.1201
Residual factor for significantly intense reflections
0.0854
Weighted residual factors for significantly intense reflections
0.1904
Weighted residual factors for all reflections included in the refinement
0.2077
Goodness-of-fit parameter for all reflections included in the refinement
