Probing the Effect of the Ligand X on the Properties and Catalytic Activity of the Complexes RuHX(diamine)(PPh3)2(X = OPh, 4-SC6H4OCH3, OPPh2, OP(OEt)2, CCPh, NCCHCN, CH(COOMe)2; diamine = 2,3-Diamino-2,3-dimethylbutane, (R,R)-1,2-Diaminocyclohexane)
Authors of publication
Clapham, Sean E.; Guo, Rongwei; Zimmer-De Iuliis, Marco; Rasool, Nailyn; Lough, Alan; Morris, Robert H.
Journal of publication
Organometallics
Year of publication
2006
Journal volume
25
Journal issue
22
Pages of publication
5477
a
12.747 ± 0.0001 Å
b
16.713 ± 0.0002 Å
c
21.85 ± 0.0003 Å
α
90°
β
93.073 ± 0.0004°
γ
90°
Cell volume
4648.24 ± 0.09 Å3
Cell temperature
150 ± 1 K
Ambient diffraction temperature
150 ± 2 K
Number of distinct elements
6
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/n 1
Hall space group symbol
-P 2yn
Residual factor for all reflections
0.0498
Residual factor for significantly intense reflections
0.0344
Weighted residual factors for significantly intense reflections
0.0797
Weighted residual factors for all reflections included in the refinement
0.0865
Goodness-of-fit parameter for all reflections included in the refinement
