Information card for entry 4074754

Structure parameters

• Formula: C27 H24 F6 N5 O6 Rh S2 Si
• Calculated formula: C27 H24 F6 N5 O6 Rh S2 Si
• SMILES: [Rh]12([Si](c3cccc4ccc[n]1c34)(c1cccc3ccc[n]2c13)C)([N]#CC)([N]#CC)[N]#CC.S(=O)(=O)([O-])C(F)(F)F.S(=O)(=O)([O-])C(F)(F)F
• Title of publication: Rhodium Complexes Containing a Tridentate Bis(8-quinolyl)methylsilyl Ligand: Synthesis and Reactivity
• Authors of publication: Sangtrirutnugul, Preeyanuch; Stradiotto, Mark; Tilley, T. Don
• Journal of publication: Organometallics
• Year of publication: 2006
• Journal volume: 25
• Journal issue: 7
• Pages of publication: 1607
• a: 15.259 ± 0.0005 Å
• b: 12.4368 ± 0.0003 Å
• c: 17.4895 ± 0.0005 Å
• α: 90 ± 0.001°
• β: 91.318 ± 0.001°
• γ: 90 ± 0.001°
• Cell volume: 3318.16 ± 0.17 ų
• Cell temperature: 140.2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/a 1
• Hall space group symbol: -P 2yab
• Residual factor for all reflections: 0.0456
• Residual factor for significantly intense reflections: 0.0456
• Weighted residual factors for all reflections: 0.0472
• Weighted residual factors for all reflections included in the refinement: 0.0472
• Goodness-of-fit parameter for all reflections included in the refinement: 1.664
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No