Information card for entry 4074909

Structure parameters

• Formula: C53 H107 Cl2 Li N4 Si6 Zr
• Calculated formula: C53 H107 Cl2 Li N4 Si6 Zr
• Title of publication: Reduction of Tetravalent Group 4 Metal Complexes Supported by an Extremely Bulky, Unsymmetrically Substituted β-Diketiminato Ligand Leading to the Regioselective CN Bond Cleavage Giving Ring-Contracted Metal-Imido Complexes
• Authors of publication: Hamaki, Hirofumi; Takeda, Nobuhiro; Tokitoh, Norihiro
• Journal of publication: Organometallics
• Year of publication: 2006
• Journal volume: 25
• Journal issue: 10
• Pages of publication: 2457
• a: 12.718 ± 0.003 Å
• b: 15.788 ± 0.004 Å
• c: 19.011 ± 0.005 Å
• α: 99.7567 ± 0.0019°
• β: 108.197 ± 0.0017°
• γ: 102.239 ± 0.002°
• Cell volume: 3427.8 ± 1.5 ų
• Cell temperature: 103 ± 2 K
• Ambient diffraction temperature: 103 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0369
• Residual factor for significantly intense reflections: 0.033
• Weighted residual factors for significantly intense reflections: 0.0774
• Weighted residual factors for all reflections included in the refinement: 0.0795
• Goodness-of-fit parameter for all reflections included in the refinement: 1.062
• Diffraction radiation wavelength: 0.7107 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No