Information card for entry 4074962

Structure parameters

• Common name: [Ru(PNNP)(OH2)2](SbF6)2
• Formula: C52.5 H37 Cl F36 N2 O2 P2 Ru Sb2
• Calculated formula: C52.929 H36 Cl1.858 F38.078 N2 O2 P2 Ru Sb2.37
• Title of publication: Chiral Dicationic Bis(aqua) Complexes [Ru(OH2)2(PNNP)]2+: The Effect of Double Chloride Abstraction on Asymmetric Cyclopropanation
• Authors of publication: Bonaccorsi, Cristina; Santoro, Francesco; Gischig, Sebastian; Mezzetti, Antonio
• Journal of publication: Organometallics
• Year of publication: 2006
• Journal volume: 25
• Journal issue: 8
• Pages of publication: 2002
• a: 12.31 ± 0.0015 Å
• b: 22.511 ± 0.002 Å
• c: 47.384 ± 0.006 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 13131 ± 3 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 9
• Space group number: 20
• Hermann-Mauguin space group symbol: C 2 2 21
• Hall space group symbol: C 2c 2
• Residual factor for all reflections: 0.064
• Residual factor for significantly intense reflections: 0.0543
• Weighted residual factors for significantly intense reflections: 0.1246
• Weighted residual factors for all reflections included in the refinement: 0.1312
• Goodness-of-fit parameter for all reflections included in the refinement: 1.09
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No