Information card for entry 4075013

Structure parameters

• Formula: C28 H48 Mo2 O4 P2 Si4
• Calculated formula: C28 H48 Mo2 O4 P2 Si4
• SMILES: [Mo]12345([PH]([P]61[Mo]1789([cH]%10[cH]9[cH]8[cH]7[cH]1%10)(C#[O])(C#[O])C6([Si](C)(C)C)[Si](C)(C)C)C([Si](C)(C)C)[Si](C)(C)C)([cH]1[cH]2[cH]3[cH]4[cH]51)(C#[O])C#[O]
• Title of publication: Arsaalkenes R−AsC(NMe2)2[R = PhC(O), 4-EtC6H4C(O), 2,4,6-Me3C6H2C(O),tBuC(O), Me3Si]: Versatile Reagents in the Chemistry of Heterocumulenes
• Authors of publication: Weber, Lothar; Bayer, Philipp; Braun, Thomas; Stammler, Hans-Georg; Neumann, Beate
• Journal of publication: Organometallics
• Year of publication: 2006
• Journal volume: 25
• Journal issue: 7
• Pages of publication: 1786
• a: 10.646 ± 0.0012 Å
• b: 11.998 ± 0.0012 Å
• c: 15.51 ± 0.0011 Å
• α: 76.572 ± 0.008°
• β: 84.597 ± 0.006°
• γ: 71.855 ± 0.009°
• Cell volume: 1830.6 ± 0.3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0305
• Residual factor for significantly intense reflections: 0.0206
• Weighted residual factors for significantly intense reflections: 0.0401
• Weighted residual factors for all reflections included in the refinement: 0.0428
• Goodness-of-fit parameter for all reflections included in the refinement: 1.072
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No