Information card for entry 4075681

Structure parameters

• Common name: (Salme*)(Salme*-H)SiPh
• Chemical name: (N,O)-N-Methyl-o-oxyacetophenoneiminato-(N',O')-N'-methyl-N'-1-(2-oxyphenyl)- vinylaminatophenylsilicon
• Formula: C24 H24 N2 O2 Si
• Calculated formula: C24 H24 N2 O2 Si
• SMILES: [Si]12(N(C(=C)c3c(O1)cccc3)C)([N](=C(c1c(O2)cccc1)C)C)c1ccccc1
• Title of publication: Equilibrium between Tetra-, Penta-, and Hexacoordinate Imine and Enamine Chelates of Silicon: Crystal Structure and Variable-Temperature NMR
• Authors of publication: Wagler, Jörg; Böhme, Uwe; Brendler, Erica; Roewer, Gerhard
• Journal of publication: Organometallics
• Year of publication: 2005
• Journal volume: 24
• Journal issue: 6
• Pages of publication: 1348
• a: 8.853 ± 0.001 Å
• b: 17.016 ± 0.001 Å
• c: 14.01 ± 0.002 Å
• α: 90°
• β: 100.385 ± 0.01°
• γ: 90°
• Cell volume: 2075.9 ± 0.4 ų
• Cell temperature: 198 ± 2 K
• Ambient diffraction temperature: 198 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0663
• Residual factor for significantly intense reflections: 0.04
• Weighted residual factors for significantly intense reflections: 0.0942
• Weighted residual factors for all reflections included in the refinement: 0.1033
• Goodness-of-fit parameter for all reflections included in the refinement: 1.016
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No