Information card for entry 4075803

Structure parameters

• Common name: 9
• Chemical name: Cyclohexyl[N-(dimethylamino)trifluoroacetimidato-N,O][N-(methylamino)trifluoroacetimidato-N,O]silicon(IV)
• Formula: C13 H20 F6 N4 O2 Si
• Calculated formula: C13 H20 F6 N4 O2 Si
• SMILES: [Si]12(OC(=NN2C)C(F)(F)F)(OC(=N[N]1(C)C)C(F)(F)F)C1CCCCC1
• Title of publication: Donor-Stabilized Silyl Cations. 9. Two Dissociation Patterns of Hexacoordinate Silicon Complexes: A Model Nucleophilic Substitution at Pentacoordinate Silicon1
• Authors of publication: Gostevskii, Boris; Silbert, Gilad; Adear, Keren; Sivaramakrishna, Akella; Stalke, Dietmar; Deuerlein, Stephan; Kocher, Nikolaus; Voronkov, Mikhail G.; Kalikhman, Inna; Kost, Daniel
• Journal of publication: Organometallics
• Year of publication: 2005
• Journal volume: 24
• Journal issue: 12
• Pages of publication: 2913
• a: 8.0658 ± 0.0016 Å
• b: 9.4973 ± 0.0019 Å
• c: 12.373 ± 0.003 Å
• α: 81.993 ± 0.003°
• β: 73.243 ± 0.003°
• γ: 83.597 ± 0.003°
• Cell volume: 896.2 ± 0.3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0324
• Residual factor for significantly intense reflections: 0.0308
• Weighted residual factors for significantly intense reflections: 0.0806
• Weighted residual factors for all reflections included in the refinement: 0.0816
• Goodness-of-fit parameter for all reflections included in the refinement: 1.053
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No