Information card for entry 4075947

Structure parameters

• Common name: (2,2,3,3-tetramethyl-1,1,4,4-tetraphenyl- 2,3-disilatetragerman-1,4-diyl)bis (triphenylphosphine)platinum
• Chemical name: (2,2,3,3-tetramethyl-1,1,4,4-tetraphenyl- 2,3-disilatetragerman-1,4-diyl)bis (triphenylphosphine)platinum
• Formula: C70 H67 Ge2 P2 Pt Si2
• Calculated formula: C70 H68 Ge2 P2 Pt Si2
• SMILES: [Pt]1([Ge]([Si]([Si]([Ge]1(c1ccccc1)c1ccccc1)(C)C)(C)C)(c1ccccc1)c1ccccc1)([P](c1ccccc1)(c1ccccc1)c1ccccc1)[P](c1ccccc1)(c1ccccc1)c1ccccc1.c1ccccc1
• Title of publication: Successive Formation of Hydrido(germyl)platinum, Germaplatinacycle, and Germylene-Bridged Dinuclear Platinum Complexes from the Reaction of a Zerovalent Platinum Complex with α,ω-Dihydrodigermanes
• Authors of publication: Usui, Yoko; Hosotani, Sayaka; Ogawa, Aki; Nanjo, Masato; Mochida, Kunio
• Journal of publication: Organometallics
• Year of publication: 2005
• Journal volume: 24
• Journal issue: 18
• Pages of publication: 4337
• a: 22.344 ± 0.002 Å
• b: 12.843 ± 0.0014 Å
• c: 22.869 ± 0.002 Å
• α: 90°
• β: 111.36 ± 0.006°
• γ: 90°
• Cell volume: 6111.8 ± 1 ų
• Cell temperature: 120 K
• Ambient diffraction temperature: 120 K
• Number of distinct elements: 6
• Space group number: 9
• Hermann-Mauguin space group symbol: C 1 c 1
• Hall space group symbol: C -2yc
• Residual factor for all reflections: 0.0419
• Residual factor for significantly intense reflections: 0.0393
• Weighted residual factors for significantly intense reflections: 0.1124
• Weighted residual factors for all reflections included in the refinement: 0.1148
• Goodness-of-fit parameter for all reflections included in the refinement: 1.051
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No