Information card for entry 4076158

Structure parameters

• Formula: C102 H78 Cl18 Co4 F12 N4 O24 P4 Pt2 S4
• Calculated formula: C102 H78 Cl18 Co4 F12 N4 O24 P4 Pt2 S4
• SMILES: c1cc2cc[n]1[Pt]1([P](c3ccccc3)(c3ccccc3)CCCC[P]1(c1ccccc1)c1ccccc1)[n]1ccc([C]34=[C]5(c6cc[n](cc6)[Pt]6([n]7ccc([C]89=[C]%102[Co]8(C#[O])(C#[O])(C#[O])[Co]9%10(C#[O])(C#[O])C#[O])cc7)[P](c2ccccc2)(c2ccccc2)CCCC[P]6(c2ccccc2)c2ccccc2)[Co]3(C#[O])(C#[O])(C#[O])[Co]45(C#[O])(C#[O])C#[O])cc1.FC(F)(S(=O)(=O)[O-])F.FC(F)(F)S(=O)(=O)[O-].C(Cl)(Cl)Cl.C(Cl)(Cl)Cl.C(Cl)(Cl)Cl.FC(F)(F)S(=O)(=O)[O-].FC(F)(F)S(=O)(=O)[O-].C(Cl)(Cl)Cl.C(Cl)(Cl)Cl.C(Cl)(Cl)Cl
• Title of publication: Self-Assembly of Cationic Pd(II)/Pt(II) Metallomacrocycles Containing Tetrahedral C2Co2Clusters from Rigid Cluster-Bridged Bipyridine (4-C5H4N)2C2Co2(CO)6and Diphosphine- or Diarsine-Chelated Pd(II)/Pt(II) Complexes [M(dppb)(H2O)2][OTf]2(M = Pd, Pt), [Pd(dpab)(H2O)(OTf)][OTf], and [Pt(dpab)(H2O)2][OTf]2
• Authors of publication: Song, Li-Cheng; Jin, Guo-Xia; Wang, Hu-Ting; Zhang, Wen-Xiong; Hu, Qing-Mei
• Journal of publication: Organometallics
• Year of publication: 2005
• Journal volume: 24
• Journal issue: 26
• Pages of publication: 6464
• a: 13.813 ± 0.006 Å
• b: 16.65 ± 0.007 Å
• c: 18.558 ± 0.008 Å
• α: 113.828 ± 0.006°
• β: 102.927 ± 0.007°
• γ: 96.944 ± 0.007°
• Cell volume: 3697 ± 3 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 10
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1103
• Residual factor for significantly intense reflections: 0.0629
• Weighted residual factors for significantly intense reflections: 0.1071
• Weighted residual factors for all reflections included in the refinement: 0.1156
• Goodness-of-fit parameter for all reflections included in the refinement: 0.876
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No