Information card for entry 4076751

Structure parameters

• Formula: C46 H20 Cl2 F12 N2 P2 Pd S2 Sb2
• Calculated formula: C60 H40.5 Cl0.7 F12 N2 P2 Pd S1.8 Sb2
• Title of publication: Palladium Complexes of a Novel Family of P,N-Chelates, the 2-(2-Pyridyl)phospholes: Synthesis, Structural Characterization, and Catalytic Activity for Olefin/CO Copolymerization
• Authors of publication: Sauthier, Mathieu; Leca, François; Toupet, Loïc; Réau, Régis
• Journal of publication: Organometallics
• Year of publication: 2002
• Journal volume: 21
• Journal issue: 8
• Pages of publication: 1591
• a: 13.655 ± 0.01 Å
• b: 14.991 ± 0.002 Å
• c: 16.835 ± 0.002 Å
• α: 108.886 ± 0.002°
• β: 108.48 ± 0.003°
• γ: 90.104 ± 0.003°
• Cell volume: 3071 ± 2 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 9
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1363
• Residual factor for significantly intense reflections: 0.0735
• Weighted residual factors for significantly intense reflections: 0.2112
• Weighted residual factors for all reflections included in the refinement: 0.2535
• Goodness-of-fit parameter for all reflections included in the refinement: 0.964
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No