Information card for entry 4076774

Structure parameters

• Formula: C27 H27 O6 Ru3 Si
• Calculated formula: C27 H27 O6 Ru3 Si
• SMILES: [Ru]1234567([Ru]89([Ru]1([Si](C)(C)c1ccccc1)(C7=O)(C#[O])C#[O])(C1(CC([c]76[cH]4[cH]3[cH]2[c]57[C]9(=[CH]81)C)C)C)(C#[O])C#[O])C#[O]
• Title of publication: Oxidative Addition of H−SiR3to Di- and Triruthenium Carbonyl Complexes Bearing a Bridging Azulene Ligand: Isolation of New Silylruthenium Complexes and Catalytic Hydrosilylation of Ketones
• Authors of publication: Matsubara, Kouki; Ryu, Kazuhiro; Maki, Tomoyuki; Iura, Takafumi; Nagashima, Hideo
• Journal of publication: Organometallics
• Year of publication: 2002
• Journal volume: 21
• Journal issue: 14
• Pages of publication: 3023
• a: 10.99 ± 0.003 Å
• b: 14.709 ± 0.005 Å
• c: 9.685 ± 0.003 Å
• α: 93.816 ± 0.012°
• β: 112.652 ± 0.006°
• γ: 77.36 ± 0.02°
• Cell volume: 1409.5 ± 0.8 ų
• Cell temperature: 183 K
• Ambient diffraction temperature: 183 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.092
• Residual factor for significantly intense reflections: 0.0676
• Weighted residual factors for significantly intense reflections: 0.1588
• Weighted residual factors for all reflections included in the refinement: 0.1791
• Goodness-of-fit parameter for all reflections included in the refinement: 1.019
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No