Information card for entry 4076803

Structure parameters

• Chemical name: Pentacarbonyl(eta$2!-methoxyvinyl-gold(I)triphenylphosphine-C,C') tungsten(0)
• Formula: C26 H20 Au O6 P W
• Calculated formula: C26 H20 Au O6 P W
• SMILES: [CH2]1=[C](OC)([W]1(C#[O])(C#[O])(C#[O])(C#[O])C#[O])[Au][P](c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Electrophilic Addition of Ph3PAu+to Anionic Alkoxy Fischer-Type Carbene Complexes: A Novel Approach to Metal-Stabilized Bimetallic Vinyl Ether Complexes
• Authors of publication: Raubenheimer, Helgard G.; Esterhuysen, Matthias W.; Timoshkin, Alexey; Chen, Yu; Frenking, Gernot
• Journal of publication: Organometallics
• Year of publication: 2002
• Journal volume: 21
• Journal issue: 15
• Pages of publication: 3173
• a: 10.698 ± 0.001 Å
• b: 12.106 ± 0.001 Å
• c: 20.352 ± 0.001 Å
• α: 90°
• β: 94.423 ± 0.001°
• γ: 90°
• Cell volume: 2627.9 ± 0.4 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0303
• Residual factor for significantly intense reflections: 0.0219
• Weighted residual factors for significantly intense reflections: 0.0441
• Weighted residual factors for all reflections included in the refinement: 0.0461
• Goodness-of-fit parameter for all reflections included in the refinement: 1.005
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No