Information card for entry 4076823

Structure parameters

• Common name: 5
• Chemical name: Bis(N-(dimethylamino)benzimidato-N,O)dibromosilicon(IV)
• Formula: C19 H23 Br3 Cl3 N4 O2 Si
• Calculated formula: C19 H24 Br3 Cl3 N4 O2 Si
• SMILES: Br[Si]12(Br)([N](C)(C)N=C(c3ccccc3)O1)[N](C)(C)N=C(c1ccccc1)O2.Br.C(Cl)(Cl)Cl
• Title of publication: Donor-Stabilized Silyl Cations 4: N-Isopropylidene Hydrazides, Novel Bidentate Ligands for Penta- and Hexacoordinate Silicon Chelates1
• Authors of publication: Kalikhman, Inna; Gostevskii, Boris; Girshberg, Olga; Krivonos, Sonia; Kost, Daniel
• Journal of publication: Organometallics
• Year of publication: 2002
• Journal volume: 21
• Journal issue: 12
• Pages of publication: 2551
• a: 13.135 ± 0.0017 Å
• b: 11.9524 ± 0.0016 Å
• c: 17.13 ± 0.002 Å
• α: 90°
• β: 101.56 ± 0.003°
• γ: 90°
• Cell volume: 2634.8 ± 0.6 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0712
• Residual factor for significantly intense reflections: 0.0474
• Weighted residual factors for significantly intense reflections: 0.1098
• Weighted residual factors for all reflections included in the refinement: 0.1163
• Goodness-of-fit parameter for all reflections included in the refinement: 0.941
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No