Information card for entry 4076840

Structure parameters

• Common name: cis-[PtCl4(NH3){C(PPh3)CO2CH3}].DMF
• Formula: C24 H29 Cl4 N2 O3 P Pt
• Calculated formula: C24 H29 Cl4 N2 O3 P Pt
• SMILES: Cl[Pt](Cl)(Cl)(Cl)([NH3])C([P+](c1ccccc1)(c1ccccc1)c1ccccc1)C(=O)OC.CN(C)C=O
• Title of publication: Synthesis of the First Family of Platinum(IV) Complexes with Phosphorus Ylide Ligands
• Authors of publication: Bokach, Nadezhda A.; Selivanov, Stanislav I.; Kukushkin, Vadim Yu.; Vicente, Jose; Haukka, Matti; Pombeiro, Armando J. L.
• Journal of publication: Organometallics
• Year of publication: 2002
• Journal volume: 21
• Journal issue: 18
• Pages of publication: 3744
• a: 10.0137 ± 0.0001 Å
• b: 10.7147 ± 0.0001 Å
• c: 27.8702 ± 0.0004 Å
• α: 79.381 ± 0.0006°
• β: 80.584 ± 0.0005°
• γ: 73.0038 ± 0.0005°
• Cell volume: 2791.5 ± 0.06 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.05
• Residual factor for significantly intense reflections: 0.0351
• Weighted residual factors for significantly intense reflections: 0.0739
• Weighted residual factors for all reflections included in the refinement: 0.0785
• Goodness-of-fit parameter for all reflections included in the refinement: 1.117
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No