Information card for entry 4077122

Structure parameters

• Formula: C79 H72.5 O2.38 P3 Ru Si2
• Calculated formula: C79 H72.5 O2.375 P3 Ru Si2
• Title of publication: Exchange Processes in Complexes with Two Ruthenium (η2-Silane) Linkages: Role of the Secondary Interactions between Silicon and Hydrogen Atoms
• Authors of publication: Atheaux, Isabelle; Delpech, Fabien; Donnadieu, Bruno; Sabo-Etienne, Sylviane; Chaudret, Bruno; Hussein, Khansaa; Barthelat, Jean-Claude; Braun, Thomas; Duckett, Simon B.; Perutz, Robin N.
• Journal of publication: Organometallics
• Year of publication: 2002
• Journal volume: 21
• Journal issue: 24
• Pages of publication: 5347
• a: 40.246 ± 0.003 Å
• b: 19.777 ± 0.003 Å
• c: 17.734 ± 0.004 Å
• α: 89.99 ± 0.02°
• β: 91.03 ± 0.02°
• γ: 90.02 ± 0.02°
• Cell volume: 14113 ± 4 ų
• Cell temperature: 160 ± 2 K
• Ambient diffraction temperature: 140 ± 2 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.0782
• Residual factor for significantly intense reflections: 0.0485
• Weighted residual factors for significantly intense reflections: 0.1119
• Weighted residual factors for all reflections included in the refinement: 0.1244
• Goodness-of-fit parameter for all reflections included in the refinement: 0.996
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No