Information card for entry 4077222

Structure parameters

• Formula: C50.25 H32.5 Au2 F10 O0.75 P2
• Calculated formula: C48 H28 Au2 F10 P2
• SMILES: [Au](c1c([P]([Au]2)(c3ccccc3)c3ccccc3)cccc1)(c1c([P]2(c2ccccc2)c2ccccc2)cccc1)(c1c(F)c(F)c(F)c(F)c1F)c1c(F)c(F)c(F)c(F)c1F
• Title of publication: Carbon−Carbon Coupling in Dinuclear Cycloaurated Complexes Containing Bridging 2-(Diphenylphosphino)phenyl or 2-(Diethylphosphino)phenyl. Role of the Axial Ligand and the Fine Balance between Gold(II)−Gold(II) and Gold(I)−Gold(III)
• Authors of publication: Bennett, Martin A.; Hockless, David C. R.; Rae, A. David; Welling, Lee L.; Willis, Anthony C.
• Journal of publication: Organometallics
• Year of publication: 2001
• Journal volume: 20
• Journal issue: 1
• Pages of publication: 79
• a: 18.534 ± 0.006 Å
• b: 21.93 ± 0.006 Å
• c: 22.122 ± 0.001 Å
• α: 90°
• β: 93.04 ± 0.02°
• γ: 90°
• Cell volume: 8979 ± 4 ų
• Cell temperature: 296.2 K
• Ambient diffraction temperature: 296.2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.104
• Residual factor for significantly intense reflections: 0.054
• Weighted residual factors for all reflections: 0.212
• Weighted residual factors for all reflections included in the refinement: 0.074
• Goodness-of-fit parameter for all reflections: 3.33
• Goodness-of-fit parameter for all reflections included in the refinement: 1.49
• Diffraction radiation wavelength: 1.5418 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No