Information card for entry 4077239

Structure parameters

• Formula: C32 H50 Cs N2 P Si2
• Calculated formula: C32 H50 Cs N2 P Si2
• Title of publication: The First Structurally Authenticated Rb−PR3and Cs−PR3Contacts. Synthesis and Crystal Structures of [Rb{(Me3Si)2CP(C6H4-2-CH2NMe2)2}]nand [Cs{(Me3Si)2CP(C6H4-2-CH2NMe2)2}(toluene)]n
• Authors of publication: Izod, Keith; Clegg, William; Liddle, Stephen T.
• Journal of publication: Organometallics
• Year of publication: 2001
• Journal volume: 20
• Journal issue: 3
• Pages of publication: 367
• a: 20.0291 ± 0.0008 Å
• b: 11.2852 ± 0.0004 Å
• c: 16.6256 ± 0.0006 Å
• α: 90°
• β: 102.999 ± 0.002°
• γ: 90°
• Cell volume: 3661.6 ± 0.2 ų
• Cell temperature: 160 ± 2 K
• Ambient diffraction temperature: 160 ± 2 K
• Number of distinct elements: 6
• Space group number: 9
• Hermann-Mauguin space group symbol: C 1 c 1
• Hall space group symbol: C -2yc
• Residual factor for all reflections: 0.0206
• Residual factor for significantly intense reflections: 0.0192
• Weighted residual factors for significantly intense reflections: 0.0392
• Weighted residual factors for all reflections included in the refinement: 0.0394
• Goodness-of-fit parameter for all reflections included in the refinement: 0.919
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No