Information card for entry 4077352

Structure parameters

• Chemical name: [Ta(N-2,6-C6H3-i-Pr2){MeC(2-NC5H4)(CH2NSiMe3)2}(O-2,6-C6H3-i-Pr2)]
• Formula: C39 H63 N4 O Si2 Ta
• Calculated formula: C39 H63 N4 O Si2 Ta
• SMILES: [Ta]12(=Nc3c(cccc3C(C)C)C(C)C)(N([Si](C)(C)C)CC(c3[n]2cccc3)(CN1[Si](C)(C)C)C)Oc1c(cccc1C(C)C)C(C)C
• Title of publication: Group 5 Imido Complexes Supported by Diamido−pyridine Ligands: Aryloxide, Amide, Benzamidinate, Alkyl, and Cyclopentadienyl Derivatives
• Authors of publication: Pugh, Stephen M.; Trösch, Dominique J. M.; Skinner, Michael E. G.; Gade, Lutz H.; Mountford, Philip
• Journal of publication: Organometallics
• Year of publication: 2001
• Journal volume: 20
• Journal issue: 16
• Pages of publication: 3531
• a: 11.51 ± 0.0003 Å
• b: 11.93 ± 0.0002 Å
• c: 14.96 ± 0.0004 Å
• α: 96.504 ± 0.002°
• β: 98.04 ± 0.001°
• γ: 92.121 ± 0.002°
• Cell volume: 2018.02 ± 0.08 ų
• Cell temperature: 150 K
• Ambient diffraction temperature: 150 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for significantly intense reflections: 0.0264
• Weighted residual factors for significantly intense reflections: 0.0295
• Goodness-of-fit parameter for significantly intense reflections: 1.0539
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No