Information card for entry 4077360

Structure parameters

• Chemical name: (eta5:eta1-1-(2-phenyl-2-diphenylphosphinoethyl)indenyl)(carbonyl)rhodium
• Formula: C30 H24 O P Rh
• Calculated formula: C30 H24 O P Rh
• SMILES: [c]123[cH]4[cH]5[c]67cccc[c]16[Rh]3457(C#[O])[P]([C@@H](C2)c1ccccc1)(c1ccccc1)c1ccccc1
• Title of publication: Induction of Planar Chirality in Formation of (η5:η1-1-(1-Cyclohexyl-2-(diphenylphosphino)ethyl)indenyl)carbonylrhodium and (η5:η1-1-(2-Phenyl-2- (diphenylphosphino)ethyl)indenyl)carbonylrhodium
• Authors of publication: Brookings, Daniel C.; Harrison, Stephen A.; Whitby, Richard J.; Crombie, Barry; Jones, Ray V. H.
• Journal of publication: Organometallics
• Year of publication: 2001
• Journal volume: 20
• Journal issue: 22
• Pages of publication: 4574
• a: 8.6414 ± 0.0002 Å
• b: 24.6807 ± 0.0005 Å
• c: 11.105 ± 0.0003 Å
• α: 90°
• β: 92.68°
• γ: 90°
• Cell volume: 2365.84 ± 0.1 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 5
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Residual factor for all reflections: 0.0513
• Residual factor for significantly intense reflections: 0.0444
• Weighted residual factors for significantly intense reflections: 0.0995
• Weighted residual factors for all reflections included in the refinement: 0.1023
• Goodness-of-fit parameter for all reflections included in the refinement: 1.083
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No