Information card for entry 4077510

Structure parameters

• Formula: C26 H27 Br3 Hg1.5 O2 P Pt
• Calculated formula: C26 H27 Br3 Hg1.5 O2 P Pt
• Title of publication: Reactivity of [M(C∧P)(acac-O,O‘)] [M = Pt, Pd; C∧P = CH2-C6H4-P(o-tolyl)2-κC,P; acac = 2,4-pentanedionato] toward HgX2(X = Br, I, CH3COO, CF3COO). New Polynuclear Complexes Containing Pt−Hg Bonds. Molecular Structures of [{Pt(C∧P)(acac-O,O‘)- HgBr(μ-Br)}2(μ-HgBr2)], an Unprecedented Square-Planar Bromomercurate Complex, and [{Pt(C∧P)(μ-O2CCH3)2Hg(μ3-acac2‒κC3,O)Hg(O2CCH3-κO)}· CHCl3]2, the First Complex Containing Asymmetric Dimercurated Acetylacetone
• Authors of publication: Ara, Irene; Falvello, Larry R.; Forniés, Juan; Sicilia, Violeta; Villarroya, Pablo
• Journal of publication: Organometallics
• Year of publication: 2000
• Journal volume: 19
• Journal issue: 16
• Pages of publication: 3091
• a: 21.787 ± 0.004 Å
• b: 8.178 ± 0.002 Å
• c: 32.205 ± 0.006 Å
• α: 90°
• β: 97.23 ± 0.03°
• γ: 90°
• Cell volume: 5692 ± 2 ų
• Cell temperature: 153 ± 2 K
• Ambient diffraction temperature: 153 ± 2 K
• Number of distinct elements: 7
• Space group number: 15
• Hermann-Mauguin space group symbol: I 1 2/a 1
• Hall space group symbol: -I 2ya
• Residual factor for all reflections: 0.1058
• Residual factor for significantly intense reflections: 0.0494
• Weighted residual factors for all reflections: 0.1388
• Weighted residual factors for significantly intense reflections: 0.1157
• Goodness-of-fit parameter for all reflections: 1.021
• Goodness-of-fit parameter for significantly intense reflections: 1.118
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No