Information card for entry 4078219

Structure parameters

• Formula: C16 H25 F3 N2 O4 Pt S Si
• Calculated formula: C16 H25 F3 N2 O4 Pt S Si
• SMILES: [Pt]1([n]2ccccc2[Si](C)(C)c2[n]1cccc2)(C)(C)(C)[OH2].S(=O)(=O)([O-])C(F)(F)F
• Title of publication: Reactivity of a Dimethylplatinum(II) Complex with the Bis(2-pyridyl)dimethylsilane Ligand: Easy Silicon‒Carbon Bond Activation
• Authors of publication: Safa, Muhieddine; Jennings, Michael C.; Puddephatt, Richard J.
• Journal of publication: Organometallics
• Year of publication: 2012
• Journal volume: 31
• Journal issue: 9
• Pages of publication: 3539
• a: 9.4577 ± 0.0003 Å
• b: 11.2012 ± 0.0004 Å
• c: 11.2937 ± 0.0004 Å
• α: 80.136 ± 0.002°
• β: 70.691 ± 0.002°
• γ: 82.773 ± 0.002°
• Cell volume: 1109.35 ± 0.07 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0271
• Residual factor for significantly intense reflections: 0.0195
• Weighted residual factors for significantly intense reflections: 0.0344
• Weighted residual factors for all reflections included in the refinement: 0.036
• Goodness-of-fit parameter for all reflections included in the refinement: 1.042
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No