Information card for entry 4078222

Structure parameters

• Formula: C21 H26 N2 O3 Pt Si
• Calculated formula: C21 H26 N2 O3 Pt Si
• SMILES: [Pt]12([OH][Si](c3[n]1cccc3)(c1[n]2cccc1)C)(C)(C)C.c1c(cccc1)C(=O)[O-]
• Title of publication: Reactivity of a Dimethylplatinum(II) Complex with the Bis(2-pyridyl)dimethylsilane Ligand: Easy Silicon‒Carbon Bond Activation
• Authors of publication: Safa, Muhieddine; Jennings, Michael C.; Puddephatt, Richard J.
• Journal of publication: Organometallics
• Year of publication: 2012
• Journal volume: 31
• Journal issue: 9
• Pages of publication: 3539
• a: 14.305 ± 0.003 Å
• b: 10.13 ± 0.002 Å
• c: 14.985 ± 0.003 Å
• α: 90°
• β: 99.04 ± 0.03°
• γ: 90°
• Cell volume: 2144.5 ± 0.8 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0366
• Residual factor for significantly intense reflections: 0.0298
• Weighted residual factors for significantly intense reflections: 0.0732
• Weighted residual factors for all reflections included in the refinement: 0.0824
• Goodness-of-fit parameter for all reflections included in the refinement: 1.071
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No