Information card for entry 4078851

Structure parameters

• Formula: C26 H43 F5 N O P2 Si V
• Calculated formula: C26 H43 F5 N O P2 Si V
• SMILES: [V]([P](C)(C)C)([P](C)(C)C)(Oc1c(F)c(F)c(F)c(F)c1F)(=NC12CC3CC(C1)CC(C2)C3)=C[Si](C)(C)C
• Title of publication: Ring-Opening Polymerization of THF by Aryloxo-Modified (Imido)vanadium(V)-alkyl Complexes and Ring-Opening Metathesis Polymerization by Highly Active V(CHSiMe3)(NAd)(OC6F5)(PMe3)2
• Authors of publication: Nomura, Kotohiro; Suzuki, Ken; Katao, Shohei; Matsumoto, Yuichi
• Journal of publication: Organometallics
• Year of publication: 2012
• Journal volume: 31
• Journal issue: 14
• Pages of publication: 5114
• a: 12.0924 ± 0.0004 Å
• b: 17.7704 ± 0.0005 Å
• c: 15.3413 ± 0.0005 Å
• α: 90°
• β: 106.018 ± 0.0007°
• γ: 90°
• Cell volume: 3168.66 ± 0.17 ų
• Cell temperature: 123 K
• Ambient diffraction temperature: 123 K
• Number of distinct elements: 8
• Space group number: 4
• Hermann-Mauguin space group symbol: P 1 21 1
• Hall space group symbol: P 2yb
• Residual factor for significantly intense reflections: 0.0517
• Weighted residual factors for all reflections included in the refinement: 0.1361
• Goodness-of-fit parameter for all reflections included in the refinement: 1.064
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No