Information card for entry 4079329

Structure parameters

• Formula: C153.5 H152 Cl7 F18 N2 O P15 Pd2 Pt4
• Calculated formula: C153.5 H152 Cl7 F18 N2 O P15 Pd2 Pt4
• SMILES: [Pt]12([Pt]34[Pd]([H][Pd]56[Pt]78[Pt]([P](C[P]8(C[P]6(c6ccccc6)c6ccccc6)c6ccccc6)(c6ccccc6)c6ccccc6)([P](C[P]7(C[P]5(c5ccccc5)c5ccccc5)c5ccccc5)(c5ccccc5)c5ccccc5)C#[N]c5c(cccc5C)C)([P](C[P]3(C[P]1(c1ccccc1)c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)[P](C[P]4(C[P]2(c1ccccc1)c1ccccc1)c1ccccc1)(c1ccccc1)c1ccccc1)C#[N]c1c(cccc1C)C.ClCCl.ClCCl.ClCCl.ClCCl.[P](F)(F)(F)(F)(F)[F-].[P](F)(F)(F)(F)(F)[F-].[P](F)(F)(F)(F)(F)[F-].O(CC)CC
• Title of publication: Hydride-Bridged Pt2M2Pt2Hexanuclear Metal Strings (M = Pt, Pd) Derived from Reductive Coupling of Pt2M Building Blocks Supported by Triphosphine Ligands
• Authors of publication: Goto, Eri; Begum, Rowshan Ara; Hosokawa, Aya; Yamamoto, Chie; Kure, Bunsho; Nakajima, Takayuki; Tanase, Tomoaki
• Journal of publication: Organometallics
• Year of publication: 2012
• Journal volume: 31
• Journal issue: 24
• Pages of publication: 8482
• a: 20.405 ± 0.004 Å
• b: 21.847 ± 0.004 Å
• c: 18.268 ± 0.003 Å
• α: 91.459 ± 0.003°
• β: 89.822 ± 0.002°
• γ: 94.575 ± 0.003°
• Cell volume: 8115 ± 3 ų
• Cell temperature: 153 ± 2 K
• Ambient diffraction temperature: 153 ± 2 K
• Number of distinct elements: 9
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for significantly intense reflections: 0.0629
• Weighted residual factors for all reflections included in the refinement: 0.193
• Goodness-of-fit parameter for all reflections included in the refinement: 1.014
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No