Information card for entry 4079899

Structure parameters

• Common name: (ON[Me]O)Si(Me)(μ-O)Si(Me)(ON[Me]O) . 2 C6H6
• Chemical name: Oxidobis(6,6'-2,4,8,10-Tetra-tert-butyl-6,12-dimethyl-12H- dibenzo[d,g][1,3,6,2]dioxazasilocine) dibenzene solvate
• Formula: C72 H104 N2 O5 Si2
• Calculated formula: C72 H104 N2 O5 Si2
• Title of publication: Migrations of Alkyl and Aryl Groups from Silicon to Nitrogen in Silylated Aryloxyiminoquinones
• Authors of publication: Shekar, Sukesh; Brown, Seth N.
• Journal of publication: Organometallics
• Year of publication: 2013
• Journal volume: 32
• Journal issue: 2
• Pages of publication: 556
• a: 13.041 ± 0.003 Å
• b: 15.124 ± 0.003 Å
• c: 18.205 ± 0.004 Å
• α: 72.58 ± 0.03°
• β: 84.92 ± 0.03°
• γ: 89.92 ± 0.03°
• Cell volume: 3411.3 ± 1.4 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0688
• Residual factor for significantly intense reflections: 0.0516
• Weighted residual factors for significantly intense reflections: 0.1256
• Weighted residual factors for all reflections included in the refinement: 0.1383
• Goodness-of-fit parameter for all reflections included in the refinement: 1.031
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No