Information card for entry 4080068

Structure parameters

• Formula: C37 H59 P2 Rh Si
• Calculated formula: C37 H59 P2 Rh Si
• SMILES: C1C[P](C(C)(C)C)(C(C)(C)C)[RhH]2([Si](c3ccccc3)(c3ccccc3)(Cc3ccccc3)[H]2)[P]1(C(C)(C)C)C(C)(C)C
• Title of publication: Multiple Si‒H Bond Activations bytBu2PCH2CH2PtBu2andtBu2PCH2PtBu2Di(phosphine) Complexes of Rhodium and Iridium
• Authors of publication: Fasulo, Meg E.; Calimano, Elisa; Buchanan, J. Matthew; Tilley, T. Don
• Journal of publication: Organometallics
• Year of publication: 2013
• Journal volume: 32
• Journal issue: 4
• Pages of publication: 1016
• a: 13.219 ± 0.01 Å
• b: 13.688 ± 0.01 Å
• c: 21.101 ± 0.016 Å
• α: 90°
• β: 107.489 ± 0.009°
• γ: 90°
• Cell volume: 3642 ± 5 ų
• Cell temperature: 105 ± 2 K
• Ambient diffraction temperature: 105 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0902
• Residual factor for significantly intense reflections: 0.0422
• Weighted residual factors for significantly intense reflections: 0.0794
• Weighted residual factors for all reflections included in the refinement: 0.0981
• Goodness-of-fit parameter for all reflections included in the refinement: 1.027
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No