Information card for entry 4080293

Structure parameters

• Common name: complex_9
• Formula: C38 H68 Si3 U
• Calculated formula: C38 H69 Si3 U
• SMILES: [CH]12=[CH]3[C]4(=[CH]5[CH]6=[C]7[CH]8=[C]1([Si](C(C)C)(C(C)C)C(C)C)[U]19%10%112345678[c]2([c]1([c]9([c]%10([c]%112C)C)C)[Si](C)(C)C)C)[Si](C(C)C)(C(C)C)C(C)C
• Title of publication: Steric Effects in the Reductive Coupling of CO by Mixed-Sandwich Uranium(III) Complexes
• Authors of publication: Tsoureas, Nikolaos; Summerscales, Owen T.; Cloke, F. Geoffrey N.; Roe, S. Mark
• Journal of publication: Organometallics
• Year of publication: 2013
• Journal volume: 32
• Journal issue: 5
• Pages of publication: 1353
• a: 26.268 ± 0.005 Å
• b: 14.737 ± 0.003 Å
• c: 24.491 ± 0.005 Å
• α: 90°
• β: 119.59 ± 0.03°
• γ: 90°
• Cell volume: 8244 ± 4 ų
• Cell temperature: 173 ± 2 K
• Ambient diffraction temperature: 173 ± 2 K
• Number of distinct elements: 4
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.117
• Residual factor for significantly intense reflections: 0.0731
• Weighted residual factors for significantly intense reflections: 0.174
• Weighted residual factors for all reflections included in the refinement: 0.2007
• Goodness-of-fit parameter for all reflections included in the refinement: 1.069
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No