Information card for entry 4080302

Structure parameters

• Common name: [Sm(DippForm)2(CH2SiMe3)(THF)]
• Formula: C65 H97 N4 O Si Sm
• Calculated formula: C65 H97 N4 O Si Sm
• SMILES: [Sm]12([O]3CCCC3)(N(C=[N]1c1c(cccc1C(C)C)C(C)C)c1c(cccc1C(C)C)C(C)C)(N(C=[N]2c1c(cccc1C(C)C)C(C)C)c1c(cccc1C(C)C)C(C)C)C[Si](C)(C)C.Cc1ccccc1
• Title of publication: Bulky Formamidinate-Supported Lanthanoid Halides and Alkyls, Including a Rare Terminal La‒Me Species
• Authors of publication: Cole, Marcus L.; Deacon, Glen B.; Junk, Peter C.; Wang, Jun
• Journal of publication: Organometallics
• Year of publication: 2013
• Journal volume: 32
• Journal issue: 5
• Pages of publication: 1370
• a: 12.858 ± 0.003 Å
• b: 13.488 ± 0.003 Å
• c: 18.772 ± 0.004 Å
• α: 108.51 ± 0.03°
• β: 93.48 ± 0.03°
• γ: 95.08 ± 0.03°
• Cell volume: 3061.4 ± 1.3 ų
• Cell temperature: 123 ± 1 K
• Ambient diffraction temperature: 123 ± 1 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0806
• Residual factor for significantly intense reflections: 0.0508
• Weighted residual factors for significantly intense reflections: 0.1078
• Weighted residual factors for all reflections included in the refinement: 0.1191
• Goodness-of-fit parameter for all reflections included in the refinement: 1.013
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No